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UPMetroSkin
Discontinued This non-official addon for Metro for Steam fixes bugs with the current version and adds optional content for you to choose from.
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InfluxDB
Power Real-Time Data Analytics at Scale. Get real-time insights from all types of time series data with InfluxDB. Ingest, query, and analyze billions of data points in real-time with unbounded cardinality.
Sadly it's part of "Steam going Backwards" program that Steam retired https://developer.valvesoftware.com/wiki/Steam_Skins which https://github.com/redsigma/UPMetroSkin used to use Steam Skin with an OPTION you seek for to remove Big Picture Button from where you pointed out but now it's gone with lots of other good features as of the August "backwards" UI update.
This will remove it from the top bar and make it a menu option. You will have to be running linux though.
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